Samsung's server memory shows up in this catalogue less as a headline brand than as the module living inside someone else's server, and this RDIMM listing fits that pattern: registered DDR4 built for multi-socket and high-capacity boards rather than a desktop tower.
The two listings differ only in how much they hold — 1×64GB — while both run the same rated 3200 MT/s CL22, so the timing question is already settled and capacity is the only real choice left.
This family is ECC and registered throughout, which means it needs a board and CPU built to address registered ECC memory; it will not fit a standard desktop socket.